Processing nanoporous organic polymers in liquid amines

• Jeehye Byun,
• Damien Thirion and
• Cafer T. Yavuz

Beilstein J. Nanotechnol. 2019, 10, 1844–1850, doi:10.3762/bjnano.10.179

• . Keywords: film; liquid amine; nanoparticles; nanoporous polymer; processibility; Introduction Nanoporous polymers offer permanent porosity along with robust and light-weight frameworks. The building-block approach for nanoporous polymers allows for a nearly infinite variety of architectures by changing

• the dissolution in the liquid amine took much longer compared to COP-100 due to the slower penetration of EDA. The rigid backbone of COP-600 with the triphenylbenzene core also contributed to the slower dissolution of polymer in EDA. As shown in Figure 5b, a red polymer solution of COP-600 could be